Palladium-catalyzed asymmetric allylic alkylation using chiral aminophosphine ligands |
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| Affiliation: | 1. College of Chemical and Biological Engineering, Hezhou University, Hezhou 542800, China;2. Department of Chemistry, Payame Noor University, Abhar, Zanjan, Islamic Republic of Iran;3. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Islamic Republic of Iran;1. Graduate Institute of Photonics and Optoelectronics, National Taiwan University, No. 1, Section 4, Roosevelt Road, Taipei 10617, Taiwan, ROC;2. Graduate Institute of Electronics Engineering, National Taiwan University, No. 1, Sec 4, Roosevelt Road, Taipei 10617, Taiwan, ROC;3. Department of Electrical Engineering, National Taiwan University, No. 1, Section 4, Roosevelt Road, Taipei 10617, Taiwan |
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| Abstract: | 
Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate 18 with a dimethyl malonate–BSA–LiOAc system has been successfully carried out in the presence of new chiral aminophosphine ligands 1–5 in good yields with good enantioselectivities (up to 85% e.e.). |
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