Aromatic polyesters from naturally occurring monosaccharides: Poly(ethylene terephthalate) and poly(ethylene isophthalate) analogs derived from D‐mannitol and galactitol |
| |
Authors: | Francisca Zamora Khalid Hakkou Abdelilah Alla Manuel Rivas Isaac Roff Manuel Mancera Sebastin Muoz‐Guerra Juan A Galbis |
| |
Institution: | Francisca Zamora,Khalid Hakkou,Abdelilah Alla,Manuel Rivas,Isaac Roffé,Manuel Mancera,Sebastián Muñoz‐Guerra,Juan A. Galbis |
| |
Abstract: | The synthesis and characterization of a new series of aromatic polyesters based on D‐mannitol and galactitol are described. These polyesters were obtained by polycondensation reaction of the terephthaloyl chloride or isophthaloyl chloride and 2,3,4,5‐tetra‐O‐methyl‐D‐mannitol or 2,3,4,5‐tetra‐O‐methyl‐galactitol in o‐dichlorobenzene. All the new polyesters were characterized by elemental analyses, GPC, IR, and NMR. They were soluble in chloroform, but insoluble in water and other polar oxygenated solvents. They showed a notable hygroscopicity, lower for those containing isophthalic units. DSC and X‐ray diffraction studies showed that D‐mannitol‐based polyesters were stiffer and less crystalline than those derived from galactitol, which presented a noticeably lower thermal stability. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4570–4577, 2005 |
| |
Keywords: | aromatic polyesters carbohydrate‐based monomers polycondensation |
|
|