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Synthesen und Kristallstrukturen neuer sulfidoverbrückter Rutheniumclusterverbindungen |
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| Authors: | Markus Wunder Amanda L. Eckermann Thomas B. Rauchfuss Dieter Fenske |
| Abstract: | Syntheses and Crystal Structures of New Sulfido‐bridged Ruthenium Clusters The reaction of S(SiMe3)2 or NaSH with [RuCl2(PPh3)3] or [Ru3Cl8(PEt3)4] leads to the formation of sulfidobridged ruthenium clusters. In this publication the compounds [Ru6S8(PPh3)6][PF6] ( 1 ), [Ru6S8(PPh3)6][RuCl4(PPh3)2] ( 2 ), [Ru6S8(PEt3)6] ( 3 ) and [Ru3S4Cl2(PPh3)3]2 ( 4 ) are described. The structures of these compounds were elucidated by single crystal X‐ray structural analyses. |
| Keywords: | Cluster compounds Sulfidobridge Phosphine Ruthenium |