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Unexpected reactivity of trifluoromethylated olefins with indole: a mechanistic investigation
Authors:Mónica S. Estevão  Filipe J.S. Duarte  Eduarda Fernandes  A. Gil Santos  M. Manuel B. Marques
Affiliation:1. REQUIMTE – Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal;2. Departamento de Ciências Químicas, Faculdade de Farmácia, Universidade do Porto, Rua Aníbal Cunha 164, 4099-030 Porto, Portugal
Abstract:
Several trifluoromethylated compounds were reacted with indole sodium salt, leading to monofluorinated compounds. The unexpected products formation was rationalized by DFT calculations.
Keywords:
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