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Effective synthesis of diiodinated picene and dibenzo[a,h]anthracene by AuCl-catalyzed double cyclization |
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| Authors: | Takahiro Nakae Ryuji Ohnishi Yoshiharu Kitahata Tatsuya Soukawa Hisako Sato Shigeki Mori Tetsuo Okujima Hidemitsu Uno Hiroshi Sakaguchi |
| Institution: | 1. Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University, Matsuyama, Ehime 790-8577, Japan;2. Department of Chemistry, Faculty of Science, Ehime University, Matsuyama, Ehime 790-8577, Japan;3. Department of Molecular Science, Integrated Center for Sciences, Ehime University, Matsuyama, Ehime 790-8577, Japan;4. Institute of Advanced Energy, Kyoto University, Uji, Kyoto 611-0011, Japan |
| Abstract: | 6,13-Diiododibenzoa,h]anthracene and 5,8-diiodopicene were synthesized by AuCl-catalyzed double cyclization. The highly selective reaction yielded a new class of peri-halogenated fused aromatics. |
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