Condensation of propargylic alcohols with indoles and carbazole in [bmim][PF6]/Bi(NO3)3·5H2O: a simple high yielding propargylation method with recycling and reuse of the ionic liquid |
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Authors: | GGKS Narayana Kumar Gopalakrishnan Aridoss Kenneth K Laali |
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Institution: | Department of Chemistry, University of North Florida, 1 UNF Drive, Jacksonville, FL 32224, USA |
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Abstract: | Propargylation of a variety of substituted indoles as well as mono- and di-propargylation of carbazole are achieved in 80–94% isolated yields by employing catalytic amounts (10 mol %) of the readily available Bi(NO3)3·5H2O in bmim]PF6] ionic liquid (IL), with repeated recycling and reuse of the IL. |
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