Regiospecific synthesis of cepanolide,a cancer chemoprotective micronutrient found in green onions |
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| Authors: | John Boukouvalas Vincent Albert |
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| Affiliation: | Département de Chimie, Pavillon Alexandre-Vachon, Université Laval, 1045 Avenue de la Médecine, Quebec City, Quebec, Canada G1V 0A6 |
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| Abstract: | The naturally occurring γ-hydroxy-β-sulfanylbutenolide cepanolide and a range of new analogues were synthesized in concise, regiospecific manner through the combined use of 2-silyloxyfuran oxyfunctionalization and tandem thio-Michael addition/elimination. |
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