Enantioselective total synthesis of heliespirone B |
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| Authors: | Akari Miyawaki Yuki Manabe Masahiro Yoshida Kozo Shishido |
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| Affiliation: | Graduate School of Pharmaceutical Sciences, The University of Tokushima, 1-78-1 Sho-machi, Tokushima 770-8505, Japan |
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| Abstract: | The first enantiocontrolled total synthesis of heliespirone B has been accomplished employing a biomimetic intramolecular oxy-Michael reaction followed by the regio- and diastereoselective reduction of the carbonyl function as key steps. |
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