The microscopic structure of bulk amorphous red phosphorus: A Raman scattering investigation |
| |
| Authors: | D.J. Olego J.A. Baumann M.A. Kuck R. Schachter C.G. Michel P.M. Raccah |
| |
| Affiliation: | Stauffer Chemical Company, Eastern Research Center, Elmsford, NY 10523, U.S.A.;Department of Physics, University of Illinois at Chicago, Chicago, IL 60680, U.S.A. |
| |
| Abstract: | The microscopic structure of bulk amorphous red P has been investigated by Raman scattering. It is concluded that the phosphorus tubes of pentagonal cross-section present in Hittorf's P and KP15 are the structural units of the amorphous red P network. Intratube and intertube correlations are responsible for intermediate range order effects. The Raman data indicate that a continuous transition from the crystalline to the amorphous state takes place for P. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
