Supported ionic liquid catalyst (Pd-SILC) for highly efficient and recyclable Suzuki-Miyaura reaction |
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| Authors: | Hagiwara Hisahiro Ko Keon Hyeok Hoshi Takashi Suzuki Toshio |
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| Affiliation: | Graduate School of Science and Technology, Niigata University, 8050, 2-Nocho, Ikarashi, Niigata, 950-2181, Japan. hagiwara@gs.niigata-u.ac.jp |
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| Abstract: | Highly efficient Suzuki-Miyaura coupling of aryl halides with arylboronic acid was realized in 50% aqueous ethanol at room temperature employing Pd(OAc)(2) immobilized in diethylaminopropylated (NDEAP) alumina pores with the aid of [bmim]PF(6), which enabled recycle use up to five times in 95% average yield and turnover number of two million. |
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