| 带官能团的双有机碘化锌试剂与酰氯的反应研究 |
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| 引用本文： | 徐长明,杨磊,黄丹凤,牛腾,胡雨来,王克虎.带官能团的双有机碘化锌试剂与酰氯的反应研究[J].有机化学,2012,32(3):574-579. |
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| 作者姓名： | 徐长明 杨磊 黄丹凤 牛腾 胡雨来 王克虎 |
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| 作者单位： | 西北师范大学化学化工学院 兰州730070 |
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| 基金项目： | 国家自然科学基金(No.20472068);甘肃省自然科学基金(No.3ZS041-A25-003);教育部高等学校博士学科点专项科研基金(No.200807360001)资助项目~~ |
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| 摘 要： | 探索了带醚键、酯基、羰基的双有机锌试剂的制备及其在CuCN 2LiCl存在下和酰氯的反应,得到了带官能团的二酮类化合物.该方法条件温和,操作简便,产率中等,提供了合成带官能团的长链二酮类化合物的一种简便方法.
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| 关 键 词： | 双有机碘化锌试剂 酰氯 二酮类化合物 |
Study on the Coupling Reaction of Fuctionalized Bisorganozinc Iodides and Acyl Chlorides |
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| Xu, Changming
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Yang, Lei
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Huang, Danfeng
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Niu, Teng
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Hu, Yulai
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Wang, Kehu.Study on the Coupling Reaction of Fuctionalized Bisorganozinc Iodides and Acyl Chlorides[J].Chinese Journal of Organic Chemistry,2012,32(3):574-579. |
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| Authors: | Xu Changming Yang Lei Huang Danfeng Niu Teng Hu Yulai Wang Kehu |
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| Institution: | Xu,Changming Yang,Lei Huang,Danfeng Niu,Teng Hu,Yulai Wang,Kehu(College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou 730070) |
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| Abstract: | This paper investigated the preparation of fuctionalized bisorganozinc iodides with ether,ester,carbonyl groups and the reactions with acyl chlorides in the presence of CuCN 2LiCl generating fuctionalized diketones.The method has the advantages of mild and simple reaction conditions with medium yields,and provides a simple synthesis procedure of fuctionalized long-chain diketone compounds. |
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| Keywords: | bisorganozinc iodide acyl chloride diketone compound |
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