| 发光的二维Cu(Ⅰ)分子箱[CuCl(DBBD)2]n |
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| 引用本文： | 胡斌,瞿志荣.发光的二维Cu(Ⅰ)分子箱[CuCl(DBBD)2]n[J].无机化学学报,2007,23(2):283-285. |
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| 作者姓名： | 胡斌 瞿志荣 |
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| 作者单位： | 东南大学化学化工学院,南京,210096 |
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| 摘 要： | Hydrothermal treatment of CuCl and atropisomeric ligand racemic-diethyl (R,S)-4,4′-biquinoline-6,6′-diethyl-3,3′-dicarboxylate (DBBD) (1) in the presence of H2O and C2H5OH over 4 days at 104～109 ℃ yielded colorless block crystals CuCl(DBBD)2]n (2). The compound exhibits strong red fluorescent emission with a wavelength of 650 nm. The crystal of CuCl(DBBD)2]n belongs to monoclinic system with space group C2/c, and a=1.656 58(17) nm, b=2.025 0(2) nm, c=1.548 73(16) nm, β=107.879(2)°, V=4.944 4(9) nm3, Dc=1.417 g·cm-3, Z=8. CCDC: 292932.
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| 关 键 词： | 一价铜 配位聚合物 合成 晶体结构 荧光 |
| 文章编号： | 1001-4861(2007)02-0283-03 |
| 修稿时间： | 2006-10-10 |
Luminescent Copper(Ⅰ) 2D Molecular Box Containing Atropisomeric Biquinoline-based Ligands |
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| HU Bin and QU Zhi-Rong.Luminescent Copper(Ⅰ) 2D Molecular Box Containing Atropisomeric Biquinoline-based Ligands[J].Chinese Journal of Inorganic Chemistry,2007,23(2):283-285. |
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| Authors: | HU Bin and QU Zhi-Rong |
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| Institution: | School of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096 and School of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096 |
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| Abstract: | Hydrothermal treatment of CuCl and atropisomeric ligand racemic-diethyl (R,S)-4,4'-biquinoline-6,6'-diethyl-3,3'-dicarboxylate (DBBD) (1) in the presence of H2O and C2H5OH over 4 days at 104～109 ℃ yielded colorless block crystals CuCl(DBBD)2]n (2). The compound exhibits strong red fluorescent emission with a wavelength of 650 nm. The crystal of CuCl(DBBD)2]n belongs to monoclinic system with space group C2/c, and a=1.656 58(17) nm, b=2.025 0(2) nm, c=1.548 73(16) nm,β=107.879(2)°, V=4.9444(9) nm3, Dc=1.417 g·cm-3, Z=8. |
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| Keywords: | coordination polymer synthesis crystal structure luminescent property |
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