| 希土与三甘醇—二(2, 2'—乙酰丙酮—4, 4'—甲基)苯基醚配合物的研究 |
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| 引用本文： | 赵翰华,单红军,王德枌,李继亮.希土与三甘醇—二(2, 2''—乙酰丙酮—4, 4''—甲基)苯基醚配合物的研究[J].无机化学学报,1995,11(1):52-56. |
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| 作者姓名： | 赵翰华 单红军 王德枌 李继亮 |
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| 作者单位： | 南京师范大学化学系，南京大学化学系 |
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| 摘 要： | 以合成的一种新化合物三甘醇－二（２，２＇－乙酰丙酮－４，４＇－甲基）苯基醚作配体，在无水甲醇中合成了七种希土氯化物的配合物，确定其组成是ＬｎＬＣｌ（Ｌｎ：Ｌａ，Ｃｅ，Ｎｄ，Ｓｍ，Ｅｕ，Ｇｄ和Ｄｙ），Ｌ：三甘醇－二（２，２＇－乙酰丙酮－４，４＇－甲基）苯基醚。由ＩＲ，ＵＶ，ＴＧ－ＤＴＧ和display status
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| 关 键 词： | 配合物 乙酰丙酮 聚醚 稀土族 苯基醚 |
| 收稿时间： | 1994/3/22 0:00:00 |
STUDIES ON THE COMPLEXES OF RARE EARTH WITH TRIETHYLENE GLYCOL-TWO(2, 2'-ACETHLACETONE-4, 4'-METHYL)PHENYLATE |
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| Zhao Hanhu,Shan Hongjun,Wang Defen and Li Jiliang.STUDIES ON THE COMPLEXES OF RARE EARTH WITH TRIETHYLENE GLYCOL-TWO(2, 2''-ACETHLACETONE-4, 4''-METHYL)PHENYLATE[J].Chinese Journal of Inorganic Chemistry,1995,11(1):52-56. |
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| Authors: | Zhao Hanhu Shan Hongjun Wang Defen and Li Jiliang |
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| Institution: | Department of Chemistry, Nanjing Normal University, Nanjing 210024,Department of Chemistry, Nanjing Normal University, Nanjing 210024,Department of Chemistry, Nanjing University, Nanjng 210093 and Department of Chemistry, Nanjing University, Nanjng 210093 |
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| Abstract: | The present paper covers seven new solid complexes of rare earth synthesized by the reaction of rare earth chlorides with triethylene glycol-two(2, 2'-accthlacetone-4, 4'-methyl) phenylate in the methanol. The complexes with a general formula: LnLCl(Ln = La, Co, Nd, Sm,Eu, Gd and Dy. L = tricthylene glycol-two(2, 2'-acethlactone-4, 4'-methyl) phenylate), were characterized by elemental analysis. chemical analysis, IR., UV., TG-DTG and 1HNMR. |
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| Keywords: | complex of rare earth acethlacetone acyclic polyether |
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