| 盐卤硼酸盐化学──ⅩⅩⅧ.氯柱硼镁石的激光拉曼光谱 |
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| 引用本文： | 夏树屏,李军,高世扬.盐卤硼酸盐化学──ⅩⅩⅧ.氯柱硼镁石的激光拉曼光谱[J].无机化学学报,1995,11(2):152-158. |
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| 作者姓名： | 夏树屏 李军 高世扬 |
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| 作者单位： | 中国科学院盐湖研究所西安二部, 710043,中国科学院盐湖研究所西安二部, 710043,中国科学院盐湖研究所西安二部, 710043 |
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| 摘 要： | 本文研究了氯柱硼镁石硼酸和硼砂的晶体和它们在水溶液中的激光拉曼光谱,并与某些阴酸盐的谱图进行对比.初步提出硼氧配阴离子的聚合形式,为进行氯柱硼镁石结构分析提供实验依据.
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| 关 键 词： | 氯柱硼镁石 硼酸盐 散射谱 硼砂 |
| 收稿时间： | 6/1/1994 12:00:00 AM |
LASER RAMAN SPECTROSCOPY OF CHLOROPINNOITE |
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| Xia Shuping,Li Jun and Gao Shiyang.LASER RAMAN SPECTROSCOPY OF CHLOROPINNOITE[J].Chinese Journal of Inorganic Chemistry,1995,11(2):152-158. |
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| Authors: | Xia Shuping Li Jun and Gao Shiyang |
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| Institution: | Institute of Salt Lakes, Academia sinica, Xian Department, Xian 710043,Institute of Salt Lakes, Academia sinica, Xian Department, Xian 710043 and Institute of Salt Lakes, Academia sinica, Xian Department, Xian 710043 |
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| Abstract: | In this paper. Laser Raman Spectra of fine crystal and aqueous solution of chloropinnoite,pinnoite, borax and bone acid have been studied. The results showed that the Raman spectra of chloropinnoite. is similar to that of pinnoite. It is suggested that both crystals of chloropinnoite and pinnoite contain the same polyborate ion B2O(OH)6]2-, and there exists different polyborate ions such as B(OH)4]-, B2O(OH)6]2-, B3O3(OH)4]- and B4O5(OH)4]2-in the aqueous solution of chloropinnoite. |
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| Keywords: | chloropinnoite borate Raman spectrum |
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