Poly(N‐Bromobenzene‐1,3‐Disulfonylamide), N,N,N′,N′‐Tetrabromobenzene‐1,3‐Disulfonylamide and DABCO‐Bromine Complex: As Novel Reagents for the Oxidative Coupling of Thiols to Disulfides |
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Authors: | Ramin Ghorbani‐Vaghei Mohammad Ali Zolfigol Nasrin Moshfeghifar Nadiya Koukabi Gholamabbas Chehardoli |
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Affiliation: | Faculty of Chemistry, Bu‐Ali Sina University, Hamadan, Iran |
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Abstract: | An efficient method for the oxidative coupling of thiols to their corresponding disulfides by new reagents poly(N‐bromobenzene‐1,3‐disulfonylamide) PBBS , N,N,N′,N′‐tetrabromobenzene‐1,3‐disulfonylamide TBBDA and DABCO‐bromine complex is described. The reaction was applicable to a variety of thiols with high chemoselectivity. |
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Keywords: | Oxidation Thiols Mercaptans Disulfides Oxidative coupling of thiols PBBS TBBDA DABCO‐bromine complex |
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