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Syntheses,electrochemical studies and crystal structures of new unsymmetrical tetrathiafulvalene carboxylate derivatives
Authors:Wei Liu  Yun‐Jun Guo  Jing‐Lin Zuo  Xiao‐Zeng You  Xi‐Rui Zeng
Institution:1. Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China;2. Department of Chemistry, Jing Gang Shan Normal College, Jian 343009, China
Abstract: chemical structure image A series of new unsymmetrical tetrathiafulvalene carboxylate derivatives ( 7‐11 ) were synthesized and characterized by NMR, MS, electrochemical studies and X‐ray crystal structural determination. Compound 8 showed obvious changes in redox peak potentials as the concentration of p‐toluenesulfonic acid changes.
Keywords:
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