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Synthesis,stereochemistry and adsorption studies of new spiranes and polyspiranes containing 1,2‐dithiolane units
Authors:Radu A. Gropeanu  Mihaela L. Ţînţaş  Catherine Pilon  Mario Morin  Livain Breau  Raluca Turdean  Ion Grosu
Affiliation:1. “Babes‐Bolyai” University, Organic Chemistry Department and CCOCCAN, 11 Arany Janos str., RO‐400028, Cluj‐Napoca, ROMANIA. Fax: 40264590818;2. Tel: 40264593833;3. Département de Chimie, Université du Québec à Montréal, H3C 3P8, CP 8888, Succ. Centre Ville, Montréal, Québec, CANADA;4. Laboratoire de Synthèse Organique Apliquée, Université du Québec à Montréal, H3C 3P8, CP 8888, Succ. Centre Ville, Montrél, Québec, CANADA
Abstract:
chemical structure image The synthesis and stereochemistry of a series of new cyclic disulfides containing (poly)spirane 1,2‐dithiolane units are reported. Also included is a study of the self‐assembled monolayers (SAMs) of these compounds on a gold surface. The characteristics of the resultant SAMs were determined by IR spectroscopy using molecular mechanics calculations.
Keywords:
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