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| 可膨胀石墨催化合成3,3,6,6-四甲基-9-芳基-1,2,3,4,5,6,7,8-八氢化氧杂蒽-1,8-二酮 | |
| 引用本文： | 张英群,王春,马晶军,高月华,耿庆芬,唐然肖,高勇军. 可膨胀石墨催化合成3,3,6,6-四甲基-9-芳基-1,2,3,4,5,6,7,8-八氢化氧杂蒽-1,8-二酮[J]. 有机化学, 2007, 27(9): 1147-1149 |
| 作者姓名： | 张英群 王春 马晶军 高月华 耿庆芬 唐然肖 高勇军 |
| 作者单位： | 河北农业大学理学院,保定,071001 |
| 基金项目： | 河北省自然科学基金（No.299158）和河北农业大学科研发展基金资助项目. |
| 摘 要： | 在可膨胀石墨催化下, 由芳香醛和5,5-二甲基-1,3-环己二酮缩合制备了3,3,6,6-四甲基-9-芳基-1,2,3,4,5,6,7,8-八氢化氧杂蒽-1,8-二酮. 在乙醇-水介质中回流反应2.5 h, 反应产率可达87%～93%. 该方法不仅反应时间短, 产率高, 而且催化剂价廉易得、对环境友好, 催化剂经简单过滤后可重复使用. |
| 关 键 词： | 可膨胀石墨 芳香醛 5,5-二甲基-1,3-环己二酮 9-芳基-1,2,3,4,5,6,7,8-八氢化氧杂蒽-1,8-二酮 |
| 收稿时间： | 2006-08-21 |
| 修稿时间： | 2006-08-212007-01-24 |
Synthesis of 3,3,6,6-Tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydro xanthene-1,8-dione Catalyzed by Expansible Graphite |
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| ZHANG,Ying-Qun,WANG,Chun,MA,Jing-Jun,GAO,Yue-Hua,GENG,Qing-Fen,TANG,Ran-Xiao,GAO,Yong-Jun. Synthesis of 3,3,6,6-Tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydro xanthene-1,8-dione Catalyzed by Expansible Graphite[J]. Chinese Journal of Organic Chemistry, 2007, 27(9): 1147-1149 | |
| Authors: | ZHANG Ying-Qun WANG Chun MA Jing-Jun GAO Yue-Hua GENG Qing-Fen TANG Ran-Xiao GAO Yong-Jun |
| Affiliation: | College of Science, Agricultural University of Hebei, Baoding 071001 |
| Abstract: | A novel synthesis of 3,3,6,6-tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydroxanthene-1,8-dione via condensation of aromatic aldehydes with 5,5-dimethyl-1,3-cyclohexanedione using expansible graphite as catalyst was described.The reaction time was 2.5 h,and the yield ranged from 87% to 93%.The catalyst was inexpensive and environmental friendly,and could be recovered by filtration. |
| Keywords: | expansible graphite aromatic aldehyde 5 5-dimethyl-1 3-cyclohexanedione 9-aryl-1 2 3 4 5 6 7 8-octahydroxanthene-1 8-dione |
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