Mechanisms of photoinduced protolytic interactions of 2,5-diphenyloxazoleortho-hydroxy derivatives in media of various acidities |
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Authors: | A D Doroshenko E A Posokhov |
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Institution: | (1) Research Institute of Chemistry, Kharkov State University, pl. Svobody 4, 310077 Ukraine, Kharkov |
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Abstract: | The mechanism of photoinduced intra- and intermolecular protolytic interactions ofortho-hydroxy derivatives of 2,5-diphenyloxazole in an aqueous alcohol medium was studied over a wide range of acidity from pH
∼13 toH
0 of ∼−7. The spectral parameters of protolytic forms and equilibrium constants were obtained, and rate constants for the primary
photochemical processes (excited-state intra- and intermolecular proton transfer reactions) were evaluated. It was shown that
the spectral characteristics of oxazoleortho-hydroxy derivatives in an acidic medium are formed as a result of competition and interchange of intra- and intermolecular
protolytic interactions. The phototautomeric form in strongly acidic solutions was found to be produced by dissociation of
the cationic form with the protonated oxazole ring. |
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Keywords: | |
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