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Tandem transformations of tetrahydropyrrolo[3,2-c]pyridines under the action of dimethyl acetylenedicarboxylate. A novel route to pyrrolo[2,3-d]azocines
Authors:L. G. Voskressensky  T. N. Borisova  T. A. Vorob’eva  A. I. Chernyshev  A. V. Varlamov
Affiliation:(1) Peoples Friendship University, 6 ul. Miklukho-Maklaya, 117198 Moscow, Russian Federation
Abstract:Reactions of substituted tetrahydropyrrolo[3,2-c]pyridines with dimethyl acetylenedicarboxylate in protic and aprotic solvents were studied. A novel single-step method for the synthesis of pyrrolo[2,3-d]azocine derivatives was developed. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2513–2519, November, 2005.
Keywords:tetrahydropyrrolo[3,2-c]pyridines  tandem opening  pyrrolo[2,3-d]azocines
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