Oxygenic polyoxometalates: a new class of molecular propellers |
| |
| Authors: | Sartorel Andrea Truccolo Melissa Berardi Serena Gardan Martino Carraro Mauro Toma Francesca Maria Scorrano Gianfranco Prato Maurizio Bonchio Marcella |
| |
| Affiliation: | ITM-CNR and Dipartimento di Scienze Chimiche, Università di Padova, Via Marzolo 1, 35131 Padova, Italy. andrea.sartorel@unipd.it |
| |
| Abstract: | ![]()
The oxygen evolving catalyst [Ru(4)(μ-OH)(2)(μ-O)(4)(H(2)O)(4)(γ-SiW(10)O(36))(2)](10-) effects H(2)O(2) dismutation at rates (k = 36.8 ± 1.4 M(-1) s(-1)), one/two order of magnitude higher compared to related tetra-substituted Cu, Fe, Mn, Ni and even Co polyoxometalates, thus providing localised oxygen gas bursts to power nano-propulsion of composite materials. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
