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A study of changes in the yields of radiolytic products in two-phase systems with tributyl phosphate
Authors:M. Hromadová  R. Čech  P. Rajec
Affiliation:(1) Department of Nuclear Chemistry, Faculty of Natural Sciences, Comenius University, 842 15 Bratislava, (Czecho-Slovakia);(2) Hygiene and Epidemiology Research Institute, 8 Ruzinovska Str., 827 99 Bratislava, (Czecho-Slovakia)
Abstract:With the aim of studying the effects of volume ratios and composition of the organic phase on the total yields of the main degradation products of tributyl phosphate (TBP) radiolysis, the following two-phase systems were used: water-TBP-carbon tetrachloride and water-TBP-n-alkane with various ratio of TBP in the organic phase and various volume ratios of organic-aqueous phases. We examined the influence of the distribution of two-phase systems components-precursors of radiolytic products on the total yields of the main radiolytic products and mechanism involved.
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