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The reaction ofC-phenylcalix[4]resorcinarene-based polymer with quaternary ammonium and potassium cations
Authors:G. N. Al'tshuler  O. N. Fedyaeva  E. V. Ostapova
Affiliation:(1) Institute of Coal and Coal Chemistry, Siberian Branch of the Russian Academy of Sciences, 18 Sovetsky prosp, 650099 Kemerovo, Russian Federation
Abstract:
The resol polycondensation ofC-phenylcalix[4]resorcinarene with formaldehyde affords a corss-linked polymer possessing ion-exchange ability. The ion-exchange capacity of the polymer with respect to NH4 +, Me4N+, Et4N+, Bu4N+, and K+ cations was determined. The equilibrium in the systemsC-phenylcalix[4]resorcinarene-based polymer—binary or ternary aqueous solutions of electrolytes was studied by potentiometric titration and quantumchemical MNDO/PM3 calculation Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1475–1477, August, 2000.
Keywords:C-phenylcalix[4]resorcinarene  polymer  quaternary ammonium bases  potassium hydroxide  ion exchange  potentiometric titration  quantum-chemical calculation  MNDO/PM3 method
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