IR- und Raman-Spektren einiger Kaliumpentafluorometallate-monohydrate |
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| Authors: | Doz Dr P Bukovec B Orel J Šiftar |
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| Institution: | 1. Laboratorium für Anorganische Chemie und Institut “Jo?ef Stefan”, Universit?t Ljubljana, Murnikova 6, YU-61001, Ljubljana, Jugoslawien
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| Abstract: | The IR- and Raman Spectra of several compounds of the stoichiometryM 2 I M IIIF5H2O and their deuterated analogs have been interpreted on the basis of their crystal structures. The compounds studied were divided into two classes regarding the bonding of water molecules. The main spectroscopic difference between the two classes was found in the region of H2O vibrations in good agreement with theoretical predictions. The metal—fluorine and metal—oxygene vibrations gave no direct information concerning the two types of water. |
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