北京城市水体的三维荧光特征

基于三维荧光光谱的水质荧光指纹法已经逐渐显示出作为水体有机物的新型表征方法的价值.本文研究了北京的城市水体的三维荧光指纹.结果表明,北京城市水体的荧光指纹可以分为3种类型:Ⅰ型有2个荧光峰,其中心分别位于λex/λem=275～280/340 nm与225～230/340 nm附近,此类水体数量最多;Ⅱ型的两个荧光中心...

Fluorescence properties of urban water bodies of Beijing

"Fluorescence fingerprint" of water body based on fluorescence excitation-emission matrix has been a novel and valuable method to exhibit the organics details. In the present study, the fluorescence matrixes of urban water bodies of Beijing were investigated. The experimental results showed that these matrixes could be divided into 3 groups: Type I owned two fluorescence centers, locating at lambda(ex)/lambda(em) = 275-280/340 and 225-230/340 nm respectively, and was the predominant group; fluorescence centers of Type II located at lambda(ex)/lambda(em) = 280/345-365 and 245/380 nm; Type II had four fluorescence centers around 275/305, 275/340, 225/305 and 225/340 nm. The fingerprints indicated that these water bodies had been disturbed by human activities. Type I and Type III were transitional fingerprints between undisturbed water body and sewage wastewater and Type III was closer to sewage wastewater. Type II closely originated from reclaimed water of municipal wastewater treatment plant. These three types were main types of urban water bodies where domestic pollution was dominating. The fluorescence fingerprints clearly displayed the ubiquitous impacts of human activities and the resulting potential risk. Fluorescence fingerprint could display pollution information and serve as a possible diagnosis tool of pollution source.