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| 大环草酰胺配合物CuC33H28Cl2N4O3的合成和晶体结构(英) | |
| 引用本文： | 周旭光,孙亚秋,王庆伦,杨光明,廖代正.大环草酰胺配合物CuC33H28Cl2N4O3的合成和晶体结构(英)[J].无机化学学报,2005,21(12):1853-1856. |
| 作者姓名： | 周旭光 孙亚秋 王庆伦 杨光明 廖代正 |
| 作者单位： | 1. 天津工业大学材化学院,天津,300160 2. 天津师范大学化学学院,天津,300074 3. 南开大学化学学院,天津,300071 |
| 基金项目： | 国家自然科学基金(No.59973008)，天津市自然科学基金(No.013603711)资助项目 |
| 摘 要： | A novel macrocyclic oxamide complex CuL (L=C33H28Cl2N4O3) has been synthesized and characterized by elemental analysis, IR spectrum, UV-Visible spectrum and single crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n. The lattice parameters are: a=0.848 8(3) nm, b=1.904 9(7) nm, c=1.868 1(7) nm, β=92.794 (6)° and V=3.016 8(19) nm3, Z=4. The results show that the coordination geometry around copper(Ⅱ) in the complex is aberrant tetragonal-plane. CCDC: 265601. |
| 关 键 词： | 大环草酰胺配合物 晶体结构 光谱表征 |
| 文章编号： | 1001-4861(2005)12-1853-04 |
| 收稿时间： | 2005-03-28 |
| 修稿时间： | 2005-09-12 |
Synthesis and Crystal Structure of Macrocyclic Oxamide Complex CuC33H28Cl2N4O3 |
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| ZHOU Xu-Guang,SUN Ya-Qiu,WANG Qing-Lun,YANG Guang-Ming and LIAO Dai-Zheng.Synthesis and Crystal Structure of Macrocyclic Oxamide Complex CuC33H28Cl2N4O3[J].Chinese Journal of Inorganic Chemistry,2005,21(12):1853-1856. | |
| Authors: | ZHOU Xu-Guang SUN Ya-Qiu WANG Qing-Lun YANG Guang-Ming and LIAO Dai-Zheng |
| Institution: | Department of Material and Chemical, Tianjin Polytechnic University, Tianjin 300160,Department of Chemistry, Tianjin Normal University, Tianjin 300074,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071 and Department of Chemistry, Nankai University, Tianjin 300071 |
| Abstract: | A novel macrocyclic oxamide complex CuL (L=C33H28Cl2N4O3) has been synthesized and characterized by elemental analysis, IR spectrum, UV-Visible spectrum and single crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n. The lattice parameters are: a=0.848 8(3) nm, b=1.904 9(7) nm, c=1.868 1(7) nm, β=92.794 (6)° and V=3.016 8(19) nm3, Z=4. The results show that the coordination geometry around copper(Ⅱ) in the complex is aberrant tetragonal-plane. CCDC: 265601. |
| Keywords: | macrocyclic oxamide complex crystal structure spectroscopic characterization |
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