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Ozonolysis of ortho-alkenylanilines |
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| Authors: | Mustafin A G Dyachenko D I Gataullin R R Ishmuratov G Yu Kharisov R Ya Abdrakhmanov I B Tolstikov G A |
| Institution: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
| Abstract: | Ozonolysis of N-acyl-2-(1-methylbut-2-enyl)- and N-acyl-2-(cyclopent-2-enyl)anilines followed by treatment with NaBH4 afforded the corresponding 2-(2-hydroxyethyl-1-methyl) and 2-(1,5-dihydroxypent-2-yl) derivatives. The reaction can be directed to indole derivatives by varying the nature of both the acyl group and reducing reagent. |
| Keywords: | ortho-alkenylanilines ozone indoles N-acetyl-2-hydroxy-3 4 4a 9a-tetrahydro-2H-pyrano[2 3-b]indole |
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