Substitutions of coordinated salicylaldehyde and its Schiff bases |
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Authors: | Sheik A Samath Kadarkaraithangam Jeyasubramanian Subramanian Thambidurai Sickandar Kamardeen Sutharavalli K Ramalingam |
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Institution: | (1) Department of Inorganic Chemistry, School of Chemistry, Madurai Kamaraj University, 625021 Madurai, India |
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Abstract: | Summary Several bis/tris-salicylaldehyde, salicylaldimine and salicyalethylenediimine chelates of cobalt(III), chromium(III), cobalt(II), nickel(II)
and copper(II) readily react with various brominating agents and undergo α-bromo/cyano/succinimido substitution, with or without
accompanying bromine substitution of the aryl ring. The selectivity of these reactions on the metal-coordinated salicylaldehyde
derivatives allows the preparation in 50–80% yield of hitherto unreported specific α-bromo products. The substituted organic
compounds could be isolated by demetallation of the chelate products. |
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