Cellulose destruction by electron-beam-induced heating |
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Authors: | Kholodkova E M Bludenko A V Chulkov V N Ponomarev A V |
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Institution: | 1.A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation ; |
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Abstract: | An efficient method for producing furfural and other furan derivatives from cellulose was proposed. Radiolytic destruction
of cotton cellulose, sulfate and sulfite pine celluloses, and carboxymethylcellulose was studied under electron-beam-induced
distillation conditions. The yield of the liquid distillate from cellulose of various origin was about 60%. Furfural and its
derivatives with the molecular weight up to 140 were the predominant products. Grinding and preheating of cellulose increase
the fraction of furan derivatives in the condensate. The liquid products are partially transformed into high-molecular-weight
compounds that are distilled with difficulty and that are involved in the formation of wood charcoal in the yield of about
20%. |
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