Palladium-catalyzed tandem cyclization/Suzuki coupling of 1,6-enynes |
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Authors: | Zhu Gangguo Zhang Zhaoguo |
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Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China. |
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Abstract: | [reaction: see text] A Pd(0)-catalyzed 1,6-enyne cyclization-arylation cascade reaction was effected via pi-allylpalladium intermediate formation and subsequent Suzuki coupling to give cyclic products with stereodefined exocyclic double bonds. |
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