Sc2@C3v(8)-C82 vs. Sc2C2@C3v(8)-C82: drastic effect of C2 capture on the redox properties of scandium metallofullerenes |
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| Authors: | Kurihara Hiroki Lu Xing Iiduka Yuko Mizorogi Naomi Slanina Zdenek Tsuchiya Takahiro Nagase Shigeru Akasaka Takeshi |
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| Affiliation: | Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan. |
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| Abstract: | ![]()
We describe the first example of scandium dimetallofullerenes, Sc(2)@C(3v)(8)-C(82), which has the same cage as the previously assigned scandium carbide cluster fullerene Sc(2)C(2)@C(3v)(8)-C(82) but they exhibit distinctly different electronic configurations and electronic behaviours, confirming the drastic influence of the internal C(2) unit. |
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