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The synthesis of phosphine derivatives of [Fe4N(CO)12]: Crystal structures of [Fe4N(CO)9(NO)(PPh3)2], [HFe4N (CO)11)PPh3)] and [(PPh3)2N][Fe4N(CO)11(PMe2Ph)] |
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| Authors: | Andr Gourdon,Yves Jeannin |
| Affiliation: | Laboratoire de Chimie des Maux de Transition, CNRS UA 419, Université P. et M. Curie, 4 Place Jussieu, 75252 Paris Cedex 05 France |
| Abstract: | Phosphines react with butterfly tetranuelear nitrido-iron clusters, [Fe4N(CO)12]− and [Fe4N(CO)11(NO)], to give mono- and di-substituted complexes. X-Ray analyses of the title compounds showed that the phosphine ligands are bound to the wing-tip atoms. |
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