X-ray structure of {[μ-N,N′-Bis(salicylidene)-1, 3-propane-diamine] (dimethylformamide) zinc(II)} dibromo cadmium(ii)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

X-ray structure of {[μ-N,N′-Bis(salicylidene)-1, 3-propane-diamine] (dimethylformamide) zinc(II)} dibromo cadmium(ii)

Authors:	Cengiz Arıcı Dinçer Ülkü Mecit Aksu Orhan Atakol

Affiliation:	(1) Department of Engineering Physics, University of Hacettepe, Ankara, Turkey;(2) Department of Chemistry, Faculty of Science, University of Erciyes, Yozgat, Turkey;(3) Department of Chemistry, University of Ankara, Ankara, Turkey

Abstract:	The title compound, forms crystals which are the orthorhombic system, space group P2₁2₁2₁, with unit cell dimensions a = 10.3928(12) Å, b = 14.6298(13) Å, c = 15.9514(11) Å, V = 2425.3(4) Å³. The cell contains four molecules. The structure is a heteronuclear dimeric complex with Zn^II and Cd^II ions. The coordination around the Zn^II ion is distorted square–pyramid and the Cd^II ion is distorted tetrahedral coordination. The Zn·sCd distance is 3.3594(7) Å.

Keywords:	Crystal structure dinuclear zinc and cadmium complex
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