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Ab initio study of structural and electronic properties of BiAlO3 and BiGaO3 |
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| Authors: | Hai Wang Biao Wang Rui Wang QingKung Li |
| Affiliation: | aSchool of Astronautics, Harbin Institute of Technology, Harbin 150001, China bSchool of Physics Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China cDepartment of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China |
| Abstract: | The first principles within the full potential linearized augmented plane wave (FP-LAPW) method was applied to study the structural and electronic properties of cubic perovskite-type compounds BiAlO3 and BiGaO3. The lattice constant, bulk modulus, its pressure derivative, band structure and density of states were obtained. The results show that BiGaO3 should exhibit higher hardness and stiffness than BiAlO3. The Al–O or Ga–O bonds are typically covalent with a strong hybridizations as well as Bi–O ones that have a significant ionic character. Both materials are weakly ionic and exhibit wide and indirect band gaps, which are typical of insulators. |
| Keywords: | Ab initio Electronic structure Perovskite structure Ferroelectrics |
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