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Photocatalysed eosin Y mediated C(sp3)-H alkylation of amine substrates via direct HAT
Authors:Vishal Srivastava  Pravin K Singh  Praveen P Singh
Institution:1. Department of Chemistry, CMP Degree College, University of Allahabad, Prayagraj 211002, India;2. Department of Chemistry, United College of Engineering & Research, Naini, Prayagraj 211010, India
Abstract:A visible light promoted, photoredox catalysed, green one-pot approach for the alkylation of amine substrates with sp2 carbon has been developed. This eosin Y based organic transformations, can behave as an effective direct hydrogen-atom transfer catalyst for coupling reaction. The proposed strategy includes simple procedure which can make adduct product with sp2 carbon. This eosin Y based photocatalytic hydrogen-atom transfer strategy may hold great potential for diverse functionalization of a wide range of native C/>H bonds in an economical and sustainable manner.</td>
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Keywords:Visible light  Eosin Y  Amine substrates  Styrene
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