| 层状氢氧化苯甲酸锌的水热合成与表征 |
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| 引用本文： | 苗建英,赵立芳,刘宗怀.层状氢氧化苯甲酸锌的水热合成与表征[J].物理化学学报,2006,22(2):193-197. |
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| 作者姓名： | 苗建英 赵立芳 刘宗怀 |
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| 作者单位： | Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007, P. R. China； 2College of Chemistry and Material Science, Shaanxi Normal University, Xi′an 710062, P. R. China |
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| 基金项目： | 中国科学院资助项目;陕西省教育厅资助项目 |
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| 摘 要： | 在110～180 ℃范围内, 以Zn(OH)2与苯甲酸为原料水热法成功合成了层状氢氧化苯甲酸锌化合物. 通过XRD、TG-DTA、SEM、TEM和元素分析研究了合成产物的结构、形貌、性质和化学组成, 探讨了合成条件对水热反应产物的影响. 当C6H5COOH/Zn的摩尔比为0.9～1.0, 水热温度130～150 ℃及水热反应12 h, 合成的层状化合物具有纤维状粒子特征, 层间距为1.44 nm, 化学组成为Zn(OH)1.12?(C6H5COO)0.88.
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| 关 键 词： | 层状化合物 氢氧化苯甲酸锌 水热合成 |
| 收稿时间： | 2005-07-06 |
| 修稿时间： | 2005-10-10 |
Hydrothermal Synthesis and Characterization of Layered Zinc Benzoate Hydroxide Compound |
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| MIAO,Jian-Ying,ZHAO,Li-Fang,LIU,Zong-Huai.Hydrothermal Synthesis and Characterization of Layered Zinc Benzoate Hydroxide Compound[J].Acta Physico-Chimica Sinica,2006,22(2):193-197. |
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| Authors: | MIAO Jian-Ying ZHAO Li-Fang LIU Zong-Huai |
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| Institution: | Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007, P. R. China； 2College of Chemistry and Material Science, Shaanxi Normal University, Xi′an 710062, P. R. China |
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| Abstract: | Layered zinc benzoate hydroxide compound with a basal spacing of 1.44 nm was prepared by hydrothermal reaction in a temperature range of 110～180 ℃. XRD, TG-DTA, SEM, TEM, and elementary analysis were used to characterize the structure, particle morphology, characteristic, and chemical composition of the synthesized layered compounds. Meanwhile, the effect of the synthetic conditions on the obtained compound was also investigated. The results indicated that when the molar ratio of C6H5COOH/Zn was 0.9～1.0, the temperature 130～150 ℃ and the reaction time 12 h, the prepared compound was of fibrous particle morphology, and its chemical formula can be written as Zn(OH)1.12?(C6H5COO)0.88. |
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| Keywords: | Layered compound Zinc benzoate hydroxide Hydrothermal Synthesis |
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