Heterobimetallic rhodium-gold halide and hydride complexes |
| |
| Authors: | Teets Thomas S Neumann Markus P Nocera Daniel G |
| |
| Institution: | Department of Chemistry, Massachusetts Institute of Technology, 6-335, 77 Massachusetts Ave., Cambridge, MA 02139-4307, USA. |
| |
| Abstract: | Heterobimetallic Rh(I)Au(I) halide complexes react with LiHBEt(3) to afford the corresponding hydride, and they are oxidised by halogen to afford thermally stable Rh(II)Au(II) complexes. The hydride complex reacts with acid and halogen sources to produce H(2) and HCl, respectively. The Rh(II)Au(II) complexes exhibit optical and photochemical properties that are derived from the bimetallic core. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
