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Highly effective and recyclable dendritic ligands for the enantioselective aryl transfer reactions to aldehydes
Authors:Liu Xin Yuan  Wu Xiao Yu  Chai Zhuo  Wu Yong Yong  Zhao Gang  Zhu Shi Zheng
Institution:Laboratory of Modern Synthetic Organic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, PR China.
Abstract:reaction: see text] A series of chiral pyrrolidinylmethanol-based dendritic ligands were synthesized for application in enantioselective aryl transfer reactions to aldehydes with the (ArBO)3/ZnEt2 system in up to 98% ee.
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