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Al‐density variation as one driving force for void formation in PERC solar cells
Authors:Renate Horbelt  Stefanie Ebert  Vaidvile Ulbikaite  Giso Hahn  Reinhart Job  Barbara Terheiden
Institution:1. Department of Physics, University of Konstanz, Konstanz, Germany;2. Department of Electrical Engineering and Computer Science, Muenster University of Applied Sciences, Steinfurt, Germany
Abstract:The reduction of void formation in local Al contact structures is of high interest in studies dealing with passivated emitter and rear contact (PERC) solar cells. So far, several processing parameters and their impact on local contact formation were investigated in detail. However, up to now density variation of Al in dependence on temperature and Si content in the melt were not taken into account as a principal reason for void formation. In this context the current assumption of a constant volume of the Al paste particles is discussed in more detail. Based on the results of energy dispersive X‐ray spectroscopy, void formation implies either an expansion of paste particles or their burst during contact formation.
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Keywords:Al paste  Si  Kirkendall effect  passivated emitter rear contact  PERC  solar cells  void
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