Adsorption effects and NMR properties: Continuous chain approach |
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Authors: | Regis Guyonnet |
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Institution: | (1) CNRS Luminy, Centre de Physique Théorique, Unité Propre de Recherche, 7061 Marseille Cedex 9, France |
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Abstract: | The NMR properties of nuclei linked to long linear polymer molecules are sensitive to the influence of hard walls. In this context, the residual energy of tensorial spin-spin interactions is calculated using a path integral approach. Several thermodynamic quantities of the polymer system (free energy, equation of state,...) are also expressed, taking chain stiffness effects and the presence of two repulsive walls into consideration. |
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Keywords: | Nuclear magnetic resonance polymers stiffness path integrals adsorption |
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