微波水热时间对C/C复合材料结构和抗氧化性能的影响

以磷酸、B4C和Al2O3为原料,采用一种新的微波水热法对C/C复合材料基体进行了抗氧化改性,重点研究了微波水热时间对改性试样物相组成、微观结构和抗氧化性能的影响。采用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、能量色散谱仪(EDS)及X射线光电子能谱(XPS)对改性后试样进行了表征。结果表明:改性后复合材料表面覆盖了一层由熔融态的HPO3、B2O3和结晶的Al(PO3)3、微量B4C粒子组成的涂层。经60~120 min的微波水热改性,复合材料的抗氧化性能随着微波水热处理时间的延长而改善,达到一定程度后,其变化不再明显。微波水热处理100 min后的试样抗氧化性能最佳,在600℃静态空气气氛下氧化16 h后,氧化失重仅为9.5×10-4 g.cm-2,氧化失重速率维持在4.46×10-5 g.cm-2.h-1的极低水平。

Influence of Time on Structure and Oxidation Resistance of Carbon/Carbon Composites Modified by a Microwave Hydrothermal Process

Carbon/carbon(C/C) composites were modified by a new microwave hydrothermal(MH) process using B4C,Al2O3 powders and phosphoric acid as source materials.The influence of the MH treatment time on the phase,microstructure and anti-oxidation property of the as-modified composites was investigated.The as-modified C/C composites were characterized by X-ray diffraction,scanning electron microscopy,energy dispersive spectroscopy and X-ray photoelectron spectroscopy techniques.Results show that the surface of the mo...