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Carbazole-oxadiazole containing polyurethanes as phosphorescent host for organic light emitting diodes |
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| Authors: | Cheng-Hsiu Ku Man-kit Leung Kuo-Huang Hsieh |
| Affiliation: | a Institute of Polymer Science and Engineering, National Taiwan University, Taipei 10617, Taiwan b Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan c Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan |
| Abstract: | New types of polyurethanes (PUs) were prepared from condensation polymerization of isophorone diisocyanate (IPDI) with various combination of 9-butyl-3,6-bis(4-hydroxyphenyl)carbazole (Cz) and 2,5-bis(4-hydroxyphenyl)-1,3,4-oxadiazole (OXD), and end-capped with 4-tert-butyl phenol. The Cz-OXD PUs can also be used as host for phosphorescent dye. Red EL emission was obtained when Ir(btp)2(acac) or Ir(2-phq)2(acac) was used as the phosphorescent dyes in Cz-OXD (3:1) PU. Maximum brightness of 394 cd/m2 and EL efficiency of 1 cd/A were achieved for the Ir(2-phq)2(acac) base device. In addition, white light PLED was demonstrated when co-dopant of Ir(btp)2(acac) and Firpic were used. |
| Keywords: | Polymeric light emitting diodes (PLEDs) Polyurethanes (PUs) Phosphorescent host Phosphorescent organic light emitting diodes (PHOLED) |
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