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Radiation induced competitive chlorination
Authors:A. De Stefanis  G. Perez  G. Caponecchi
Affiliation:(1) Istituto di Cromatografia del CNR, Area della Ricerca, c. p. 10, 00016 Monterotondo Stazione (RM), Italy
Abstract:
The gamma-radiolysis of solutions of benzene and naphthalene in carbon tetrachloride has been studied to obtain information about chlorination reactions. The agr position of naphthalene showed a reactivity 2.5 higher with respect to benzene, while the absence of 2-chloronaphthalene among the products confirmed the relatively high activation energy required for the attack in beta position.
Keywords:
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