Reaction between triphenylphosphine and aromatic amines in the presence of diethyl azodicarboxylate: an efficient synthesis of aryliminophosphoranes under neutral and mild conditions |
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| Authors: | Mehdi Adib Ehsan SheikhiAzadeh Deljoush |
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| Institution: | School of Chemistry, University College of Science, University of Tehran, PO Box 14155-6455, Tehran, Iran |
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| Abstract: | An efficient synthesis of aryliminophosphoranes is described. A mixture of an aromatic amine, diethyl azodicarboxylate and triphenylphosphine undergo a Mitsonobu type reaction at ambient temperature in dry dichloromethane to afford aryliminophosphoranes in excellent yields. |
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| Keywords: | Aryliminophosphoranes Triphenylphosphine Diethyl azodicarboxylate Mitsonobu reaction |
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