| ~(14)N ENDOR Study on Bis(2-Hydroxylphenyl Ketoxime)-~(63)Cu(Ⅱ) Complex |
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| 作者姓名： | 徐元植 陈德余 程朝荣 宫本量 大庭裕范 岩泉正基 周澄明 陈耀焕 |
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| 作者单位： | Department of Chemistry，Zhejiang University，Hangzhou 310027，PRC，Department of Chemistry，Zhejiang University，Hangzhou 310027，PRC，Department of Chemistry，Zhejiang University，Hangzhou 310027，PRC，Institute for Chemical Reaction Science，Tohoku University，Sendai，980，Japan，Institute for Chemical Reaction Science，Tohoku University，Sendai，980，Japan，Institute for Chemical Reaction Science，Tohoku University，Sendai，980，Japan，Shanghai Institute of Organic Chemistry，Academia Sinica，Shanghai 200032，PRC，Shanghai Institute of Organic Chemistry，Academia Sinica，Shanghai 200032，PRC |
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| 摘 要： | The ENDOR spectrum of ~(14)N-~(63)Cu-HAP complex in DMSO/EtOH (5:1) freezing solution at 20 K has been studied using orientational selective method in this paper. The anisotropic superhyperfine coupling tensor and qusdrupole coupling tensor of ligand ~(14)N nucleus, and the superhyperfine coupling tensor of various ~1H nuclei have been measured precisely. Comparing the superhyperfine coupling tensor of ~(14)N-nucleus with previous work shows that the analytical method of spectrum is reasonable and the data are reliable in our previous work.
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