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Investigation of segmental reorganization within amphiphilic block polymer nanoparticles derived from shell crosslinked micelle templates: Shell crosslinked knedel-like inversion
Authors:Qi Zhang  Karen L Wooley
Institution:1. Experimental work was conducted at Washington University in Saint Louis, Department of Chemistry, Saint Louis, MO 63130 USA

Present address: Microsoft Corporation, One Microsoft Way, Redmond, WA 98052 USA;2. Department of Chemistry, Texas A&M University, College Station, Texas, 77842

Abstract:The construction of nanoscopic materials by synthetic methodologies that iterate covalent and supramolecular interactions has been developed over the past three decades as a powerful method to afford complex functional materials. Indeed, the present study was nearly lost in the archives of dissertation research completed in 2001, which revealed nanoscale conformational dynamics in the segmental reorganization, and partial inversion, of topologically shell crosslinked knedel-like (SCK) nanoparticles. © 2019 Wiley Periodicals, Inc. J. Polym. Sci. 2020 , 58, 204–214
Keywords:amphiphilic  block polymer  inverse micelle  polymer micelle  shell crosslinked nanoparticle
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