Effects of Solvent and Reaction Time in Sonochemical Synthesis of Cadmium(II) Compounds and Use them as Template for Synthesis of Cadmium(II) Oxide Nano Structures |
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| Authors: | Bagher Souri Ali Reza Rezvani Soheila Abbasi Payam Hayati Jan Janczak |
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| Institution: | 1. Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, P.O. Box 98135–674 Zahedan, Iran;2. Institute of Low Temperature and Structure Research, Faculty of Sciences, Polish Academy of Sciences, 50–950 Wroclaw, Poland |
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| Abstract: | Abstract . A cadmium(II) zero-dimensional supramolecular compound Cd(L)2(I)2] ( 1 ), {L = 2-picolylamine}, was fabricated by branch tube and sonochemical irradiation techniques. Regardless of the method utilized, the same crystallographic structure is obtained for the complex. To investigate the effects of reaction time and solvent on the creation of Cd(L)2(I)2] ( 1 ) supramolecule compound, certain tests were designed and four specimens of 1 were fabricated through sonochemical process. Less reaction time led to the creation of smaller particles with mixed morphologies. To prepare cadmium(II) oxide micro-crystals via calcination, four samples were utilized as new precursors. Micro- and nano-sphere of cadmium(II) oxide could be fabricated from 1. The morphology and structure of micro- and nano-crystals were identified by using Scanning Electron Microscopy (SEM), IR spectroscopy, and X-ray powder diffraction (XRD). |
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| Keywords: | Solvent effect Sonochemical method Supramolecule compound Hirshfeld surface analysis |
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