乙酰苦玄参甙元(Ⅰ)的晶体结构测定

苦玄参甙元(I)为植物苦玄参的有效成分之一。乙酰苦玄参甙元(I)(k×k)为其乙酰化合物,分子式为C₃₄H₄₈O₇,属正交晶系,空间群为D₂⁴-P2₁ 2₁ 2₁,晶胞参数为a=22.357(10)?,b=15.277(8)?,c=9.089(4)?。晶胞内分子数z=4。用PW-1100四圆衍射仪收集衍射强度数据,独立衍射点为2234个。用直接法(MULTAN-78)测定晶体结构。结构参数的修正采用全矩阵最小二乘法,R=0.1099,由差值Fourier综合得到氢原子位置。 关键词：

DETERMINATION OF ACETYL PICRIAFELTARRAGENIN COMPOUND CRYSTAL STRUCTURE

Acetyl pieriafeltarragenin compound is an acetyl compound of picriafeltarra-genin which is one of effective component of plant Picria Fel-Tarrae Lour. The mole-cular formula is C₃₄H₄₈O₇. Space group is D₂⁴-P2₁ 2₁ 2₁. The cell dimensions are a=22.357(10)?,b=15.277(8)?,c=9.089(4)?. Four molecules are contained in a cell (z=4).The intensity data were collected on a PW-1100 four circle diffractometer. The total number of independent reflections amounts to 2234. The crystal structure has been determined by direct method (MULTAN-78),and the structure parameters have been refined by means of full matrix Least.squares method to R=0.1099. The difference Fourier Syntheses gives out all the hydrogen positions.
Keywords：