| 六氰合铁酸铜钴薄膜修饰电极的in-situ FTIR研究 |
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| 引用本文： | 崔兴品,汪夏燕,林祥钦.六氰合铁酸铜钴薄膜修饰电极的in-situ FTIR研究[J].光谱学与光谱分析,2003,23(3):603-604. |
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| 作者姓名： | 崔兴品 汪夏燕 林祥钦 |
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| 作者单位： | 中国科学技术大学化学系,安徽,合肥,230026 |
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| 基金项目： | 国家自然科学基金 (No 2 0 0 750 2 5)资助课题 |
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| 摘 要： | 本文用循环伏安法在铂电极的表面电沉积了六氰合铁酸铜钴薄膜，结合电化学方法，研究了修饰膜氧化过程中的现场红外光谱。
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| 关 键 词： | 六氰合铁酸铜钴薄膜 修饰电极 in－situFTIR 电化学 红外光谱 铂电极 导电聚合物 |
| 文章编号： | 1000-0593(2003)03-0603-02 |
| 修稿时间： | 2001年11月5日 |
In-situ FTIR Study of Hybrid Copper-cobalt Hexacyanoferrate Film Modified Electrode |
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| CUI Xing-pin,WANG Xia-yan and LIN Xiang-qin.In-situ FTIR Study of Hybrid Copper-cobalt Hexacyanoferrate Film Modified Electrode[J].Spectroscopy and Spectral Analysis,2003,23(3):603-604. |
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| Authors: | CUI Xing-pin WANG Xia-yan and LIN Xiang-qin |
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| Institution: | Department of Chemistry, University of Science and Technology of China, Hefei 230026, China. |
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| Abstract: | The study on the in-situ FTIR spectroelectrochemistry of a hybrid copper-cobalt hexacyanoferrate film modified platinum electrode was carried out. The variation of the FTIR spectra was well correlated to the redox process of CuCoHCF. The relative contribution of Cu(II) and Co(II) to the stretching vibration of CN was found to vary with the applied potential. |
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| Keywords: | Hybrid copper-cobalt hexacyanoferrate In-situ FTIR Spectroelectrochemistry |
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