Supramolecular control in carbohydrate epimerization: discovery of a new anion host-guest system |
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| Authors: | Dong Hai Rahm Martin Brinck Tore Ramström Olof |
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| Affiliation: | Department of Chemistry, KTH-Royal Institute of Technology, Teknikringen 30, S-10044 Stockholm, Sweden |
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| Abstract: | ![]()
A new anion-carbohydrate recognition system is described. Pyranosides with axial protons in 1-, 3-, and 5-position proved efficient, forming relatively strong complexes between the anion and the B-face of the carbohydrate. This system could furthermore be used in supramolecular control in Lattrell-Dax epimerization reactions, leading to either activation or deactivation effects. |
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